The bimolecular rate constants obtained for sulphanilic acid and sulphanilamide approach the diffusion controlled limit for this process in the case of NOCl and NOBr, Also reported is a study of the diazotisation of two heteroaromatic amines: 2 amino 5 nitrothiazole and 3 amino l,2 steroids,4 triazoleo Catalysis by acid and the nucleophiles Cl and SCN has been observed. The catalytic and reactivity trends described above have been noted for reaction of these heteroaroraaticso The Pk(_a) value for 2 amino 5 nitrothiazole has been determined and agrees well with the literature values. In addition to the above studies of diazotisation mechanisms, results are reported of a study of the leaving abilities of various electrofugal leaving groups X during ipso=coupling of 4=nitroaniline with 4 X,N dimethylanilineso The sequence of leaving abilities has been determined by product yield studies.

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